New heterocorroles and norcorroles from dipyrrin metal complexes
Séminaire Chimie ED459
Prof. Hiroshi
Le Jeudi 03 Octobre 2019 à 14h
ENSCM, Amphithéâtre Godechot (campus Balard, 240 av. Émile-Jeanbrau)
Date de début : 2019-10-03 14:00:00
Date de fin : 2019-10-03 15:00:00
Lieu : ENSCM amphi Godechot (campus Balard, 240 av E. Jeanbrau)
Intervenant : Prof. Hiroshi
Dept of Molecular and Macromolecular Chemistry, Graduate School of Engineering, Nagoya University, Japan
We have developed a metal-templated strategy to access novel various porphyrinoids. Dipyrrin metal complexes are a nice precursor to prepare 10-heterocorroles containing various heteroatoms (N, S, Si, P, and B) as well as norcorroles. 10-Heterocorroles exhibit tunable optical and electronic properties depending on the heteroatoms. Norcorroles are a strongly antiaromatic porphyrinoid, which shows various interesting properties such as three-dimensional aromaticity by stacking.
Contact local ICGM : Dr. Sébastien
