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Séminaire Chimie ED459

New heterocorroles and norcorroles from dipyrrin metal complexes

Prof. Hiroshi Shinokubo (Department of Molecular and Macromolecular Chemistry, Graduate School of Engineering, Nagoya University, Japan)

publié le

Le Jeudi 03 Octobre 2019 à 14h
ENSCM, Amphithéâtre Godechot (campus Balard, 240 av. Émile-Jeanbrau)

We have developed a metal-templated strategy to access novel various porphyrinoids. Dipyrrin metal complexes are a nice precursor to prepare 10-heterocorroles containing various heteroatoms (N, S, Si, P, and B) as well as norcorroles. 10-Heterocorroles exhibit tunable optical and electronic properties depending on the heteroatoms. Norcorroles are a strongly antiaromatic porphyrinoid, which shows various interesting properties such as three-dimensional aromaticity by stacking.

Contact local ICGM : Dr. Sébastien Richeter (équipe CMOS)


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